【摘 要】
：
One of the crucial parameters determining the electron transfer rate,Franck Condon factor, sas evaluated quantitatively for electron exchange reactions involv
【出 处】
：
Chinese Chemical Letters
论文部分内容阅读
One of the crucial parameters determining the electron transfer rate,Franck Condon factor, sas evaluated quantitatively for electron exchange reactions involving hexaquo-metal ions. Adopting appropriate spectroscopic and photoemission data, reasonable results were obtained and compred in terms of ciassical and quantum-mechanical theory.Investigation shoWs that for such reactirm occurred at ran temPerature, nuclear tunnling effects increase the absolute rates ty several times, chich are not draretic bot still should be considered for cmplementary PUrpose
One of the crucial parameters determining the electron transfer rate, Franck Condon factor, sas evaluated quantitatively for electron exchange reactions involving hexa-metal ions. Adopting appropriate spectroscopic and photoemission data, reasonable results were obtained and compred in terms of ciassical and quantum-mechanical theory .Investigation shoWs that for such reactirm occurred at ran temPerature, nuclear tunnling effects increase the absolute rates ty several times, chich are not draretic bot still should be considered for cmplementary PUrpose
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