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Solvothermal reactions of MnCl2·4H2O with(pyridin-2-yl)methyl 4-(2-(4-((pyridin-2-yl)methoxy)phenyl)diazenyl)benzoate(L1) via an in situ ligand transformation reaction produced a new coordination polymer, {[Mn2.5Cl3L2(H2O)]·H2O}n(1, where HL = 4