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<正>A new cobalt(Ⅱ)polymer with quasi-rectangular cavities,[Co(L)_2(TP)·H_2O]_n 1(L =1-butylbenzimidazole,TP=terephthalate ion)has been prepared by means of self-assembly of 1-butylbenzimidazole,terephthalic acid and Co(NO_3)_2·6H_2O.The st