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采用控制电位下的恒载荷拉伸试验测得LC4铝合金在30℃、50℃、90℃的0.5mol/LNaCl水溶液(pH=7)中的应力腐蚀临界破裂电位Ecri分别为-720mV、-760mV、-850mV(SCE).体系电位负于Ecri时不发生应力腐蚀破裂.Ecri随介质温度T升高而向负方向移动,Ecri与T大体呈直线关系:Ecri=-A155-2.17T(mV).用改进的模拟闭塞电池研究了裂纹尖端化学状态的变化:当通入闭塞区的阳极电流密度为1mA/cm2时,其溶液pH值从7降至3.3,Cl-浓集倍数高达4.断口呈典型的沿晶应力腐蚀开裂形貌.
The critical stress of rupture potential (Ecri) of LC4 aluminum alloy in 0.5 mol / L NaCl aqueous solution (pH = 7) at 30 ℃, 50 ℃ and 90 ℃ was -720mV, 760mV, -850mV (SCE). Stress corrosion cracking does not occur when the system potential is negative to Ecri. Ecri moves in the negative direction as the temperature T of the medium increases, and Ecri is generally in a linear relationship with T: Ecri = -A155-2.17T (mV). A modified simulated occlusion cell was used to investigate the chemical state of the crack tip: when the anode current density into the occluded region was 1mA / cm2, the pH value of the solution dropped from 7 to 3.3 and the concentration of Cl- was up to 4. The fracture is a typical intergranular stress corrosion cracking morphology.