【摘 要】
:
A glycinato copper compound {Cu(NH2CH2COO)(H2O)ClO4} crystallizes in monoclinic, space group P21/n with a = 7.8299(9), b = 10.3807(10), c = 9.4775(12)(A), β =
【机 构】
:
State Key Laboratory of Structural Chemistry
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A glycinato copper compound {Cu(NH2CH2COO)(H2O)ClO4} crystallizes in monoclinic, space group P21/n with a = 7.8299(9), b = 10.3807(10), c = 9.4775(12)(A), β = 109.659(6)°, V = 725.43(12)(A)3, Z = 4, Mr = 255.07, Dc = 2.335 g/cm3, F(000) = 508, μ = 3.381 mm-1, R = 0.0270 and wR = 0.0707 for 1677 observed reflections with I > 2σ(I). The title compound contains a chain in the syn-anti conformation, which is generated by the glide-plane operation. The adjacent layers made up of the chains through the connection of perchlorate are related by inversion center ope- ration, which links with each other through the hydrogen bonds.
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