【摘 要】
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Hydrogen transfer reaction catalyzed by transition metal complexes has been studiedWidely. The unsaturated alcohols can be isomerized to aldehydes or ketones b
【出 处】
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Acta Chimica Sinica(English Edition)
论文部分内容阅读
Hydrogen transfer reaction catalyzed by transition metal complexes has been studiedWidely. The unsaturated alcohols can be isomerized to aldehydes or ketones by intra-molecular hydrogen transfer reaction. R~1R~2C=CHCH(OH)R~3R~1R~2CHCH_2COR~3In this reaction, hydrogenation of olefins and the oxidation of alcohols can be carried out sim-ultaneously under mild conditions without the addition of any other, therefore, thisreaction has useful applications in organic synthesis.
Hydrogen transfer reaction catalyzed by transition metal complexes has been studied. The unsaturated alcohols can be isomerized to aldehydes or ketones by intra-molecular hydrogen transfer reaction. R ~ 1R ~ 2C = CHCH (OH) R ~ 3R ~ 1R ~ 2CHCH_2COR ~ 3In this reaction, hydrogenation of olefins and the oxidation of alcohols can be carried out sim-ultaneously under mild conditions without the addition of any other, therefore, thisreaction has useful applications in organic synthesis.
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