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近年来,我们曾报道了莰烯-三环烯在氢型丝光沸石催化下与开链醇及二醇等进行烷氧基化反应的结果。最近,Scheidll,Fran报道用浓硫酸催化莰烯与环戊醇反应,合成exo-1,7,7-三甲基双环[2.2.1]庚基环戊醚。
In recent years, we have reported the acenaphthylene - tricyclic olefin in the hydrogen-type mordenite catalyst with the open-chain alcohols and diols and other alkoxylation reaction results. Recently, Scheidll, Fran reported the use of concentrated sulfuric acid catalyzed acenaphthylene with cyclopentanol to synthesize exo-1,7,7-trimethylbicyclo [2.2.1] heptylcyclopentyl ether.