【摘 要】
：
A novel Cd(Ⅱ) coordination polymer,{[Cd3(tzo)2(suc)(H2O)6]·(suc)}n (Htzo = 1,2,4-triazole,H2suc = succinic acid),has been synthesized from the reaction of aqu
【机 构】
：
Department of Chemistry,College of Chemistry and Life Science
论文部分内容阅读
A novel Cd(Ⅱ) coordination polymer,{[Cd3(tzo)2(suc)(H2O)6]·(suc)}n (Htzo = 1,2,4-triazole,H2suc = succinic acid),has been synthesized from the reaction of aqueous solution of niques,and structurally characterized by X-ray analysis and spectral techniques.To the best of our knowledge,among the few documented triazole-cadmium coordination polymers,this complex presents a novel configuration.The deprotonated 1,2,4-triazole is in tridentate and succinate in bis-chelate modes to link the Cd(Ⅱ) centers,generating a 2-D grid-like network topology.Thermogravimetric analysis results show that the framework architecture is a stable porous material.The fluorescent emission has also been discussed.
其他文献
Energetic and electronic structures of the on-top Al13Inm (n = 1 ～12,m = -1,0,+1)clusters have been investigated by employing a first-principles pseudo-potential
A polynuclear complex [Cd(endc)(H2O)]n·nH2O (endc = endo-norbomene-cis5,6-dicarboxylate anion) has been synthesized by the hydrothermal reaction of cadmium nit
Three kinds of new layered perovskite compounds with Ruddlesden-Popper (R-P) phase, AgxNa2-xLa2Ti3O10 (x = 0.2, 0.3 and 0.5), were synthesized by an ion-exchang
By means of a relativistic effective potential, we analytically research competition between the quarkLasinio (NJL) model and obtain the Gs-Hs phase diagram, wh
We present the continuous state vector of the total coordinate of multi-particle and the state vector of their total momentum, respectively, which possess compl
A scheme for generating cluster states via Raman interaction is proposed. In the scheme, we firstly prepare cluster states of multi-cavities with information en
It has been proved that there exists a cross coupling between vertical heat turbulent transport and vertical velocity by using linear thermodynamics. This resul
A sequential method for the determination of dimethyl sulfur compounds, including dimethylsulfide (DMS), dimethylsulfoniopropionate (DMSP) and dimethylsulfoxide
为探究吕家坨井田地质构造格局,根据钻孔勘探资料,采用分形理论和趋势面分析方法,研究了井田7
We present a comparative study of the ground state of the one-dimensional Hubbard model. We first use a new fermion coherent state method in the framework of Fe