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The title compound 2-hydroxy-5-(4-hydroxy-3-phenyliminomethyl-benzyl)-benzyli-dene-phenyl-amine(C27H22N2O2, Mr = 406.47) was synthesized by 5,5’-methylene-bissalicylal-dehyde with aminobenezene, and its crystal structure was determined by single-crystal X-ray diffraction.The crystal belongs to the monoclinic system, space group C2/c with a = 4.4026(6), b = 1.501(13), c = 0.95818(12) nm, β = 90.868(2)o, V = 4.2813(9) nm3, Z = 8, Dc = 1.292 g/cm3, μ = 0.010, F(000) = 1744, R = 0.0576 and wR = 0.1450 for 3766 observed reflections with I > 2σ(I).X-ray analysis reveals that the molecule has a pair of intramolecular O-H···N hydrogen bonds.
The title compound was synthesized by 5,5’-methylene-bissalicylal-dehyde with aminobenezene (C27H22N2O2, Mr = 406.47) , and its crystal structure was determined by single-crystal X-ray diffraction. The crystal belongs to the monoclinic system, space group C2 / c with a = 4.4026 (6), b = 1.501 (13), c = 0.95818 (12) nm, Z = 8, Dc = 1.292 g / cm3, μ = 0.010, F (000) = 1744, R = 0.0576 and wR = 0.1450 for 3766 observed reflections with I> 2σ (I). X-ray analysis reveals that the molecule has a pair of intramolecular OH ··· N hydrogen bonds.