【摘 要】
:
A novel hydrogen-bonded organic frameworks (HOFs) FJU-200 has been constructed from N,N\'-bis(5-isophthalic acid)naphthalimide (H4L).FJU-200 has a good dual-function of aniline and ultraviolet detection.FJU-200 is the first case of HOF with dual sensing
【机 构】
:
Fujian Provincial Key Laboratory of Polymer Materials,College of Chemistry and Materials Science,Fuj
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A novel hydrogen-bonded organic frameworks (HOFs) FJU-200 has been constructed from N,N\'-bis(5-isophthalic acid)naphthalimide (H4L).FJU-200 has a good dual-function of aniline and ultraviolet detection.FJU-200 is the first case of HOF with dual sensing of visual color changes and photoluminescence quenching for aniline detection,and the detection limit of aniline can reach 5.5 × 10-4 mol/L.Under ultraviolet FJU-200 will rapidly change from light yellow to rustic brown,which makes it possible to use FJU-200 to achieve minute-level ultraviolet detection.Moreover,for more convenient use,FJU-200 test papers are prepared.Using them,convenient and fast aniline or ultraviolet detection can be realized.The single-crystal X-ray structures show that compared with the original FJU-200,both PhNH2@FJU-200 and UV-FJU-200 have larger pore sizes,and the dihedral angles of the H2L2-in framework has been changed.
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