【摘 要】
：
A novel complex ZnTPPL1·3DMF 1 (TPP=tetraphenylporphyrin, L1=N-(4-(9-carbazolyl) phenyl)-N,N-di(4-pyridyl)amine) was prepared by a hydrothermal method and char
【机 构】
：
Key Laboratory for Advanced Materials and Institute of Fine Chemicals,Department of Chemistry
论文部分内容阅读
A novel complex ZnTPPL1·3DMF 1 (TPP=tetraphenylporphyrin, L1=N-(4-(9-carbazolyl) phenyl)-N,N-di(4-pyridyl)amine) was prepared by a hydrothermal method and characterized by elemental analysis, IR, and single-crystal X-ray diffraction analysis. Compound 1crystallizes in triclinic, space group P(1) with a=13.3082(2), b=14.3276(2), c=18.6120(3) (A), a =109.853(1), β=95.054(1), γ=98.832(1)°, V=3260.57(9) (A)3, Z=2, Dc=1.334g/cm3,C81H69N11O3Zn, Mr=1309.84, μ(MoKa)=0.438 mm-1, F(000)=1372, GOF=1.159, the final R=0.0482 and wR=0.1479 for 12091 observed reflections (I＞2σ(I)). Crystal structure analyses complex. The binding constant was estimated to be 1.74(7)×104 M-1 from electronic spectra measurements.
其他文献
A Quantitative Structure-activity Relationship (QSAR) model was developed topredict the hallucinogenic activity of phenylalkylamines by Artificial Neural Networ
A simple and general strategy is described for preparing network supported catalyst through a one-pot synthetic procedure using supramolecular gel as template.
A series of heterocycle-substituted phthalimide derivatives were synthesized. Structurally diverse derivatives with heterocyclic rings, including furan, imidazo
Green, mild and efficient iodination of hydroxylated aromatic aldehydes and ketones using iodine and iodic acid in the solid-state by grinding under solvent-fre
N-m-cyanophenyl-o-aminobenzoato acid (C15H11N2O2, HNCAB) ligand was synthesized through the bromination and nucleophilic reactions. The compound [K(NCAB)]n (1)
A new complex constructed from a unit with two As3O6 rings capping Andersontype moieties, [Ni(en)2(H2O)2]2[(NiO6)Mo6O18(As3O3)2]·2H2O (1, en = ethylenediamine)
Activated carbon derived from solid hazardous waste scrap tires was evaluated as a potential adsorbent for cationic dye removal. The adsorption process with res
The title compound 2-(spirobifluorene-2-yl)-3,4-diaza-spirobifluorene (C48H28N2,Mr = 632.72) has been synthesized and characterized by 1H NMR, 13C NMR and singl