应用Fick定律计算CO/H2+N2混合气体还原铁矿石动力学参数的偏差

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为了讨论采用Fick定律未反应核模型(Fick模型)计算CO/H2+N2混合气体还原铁矿石动力学参数的偏差,建立基于Maxwell-Stefan关系式的未反应核模型(M-S模型),对Fick模型计算得到的动力学参数和M-S模型中设定的动力学参数进行比较分析.结果表明:N2对CO/H2还原FeO的阻碍作用与其摩尔分数成正比;N2对正反应速率常数的计算没有影响;CO-N2体系中Fick模型所用的互扩散系数小于实际值,而H2-N2体系中其所用的互扩散系数大于实际值.
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