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A new Zn(Ⅱ) coordination polymer, [Zn(4-PP)(1,4-BDC)?(H2O)]n(1, 4-PP = 4-(1 H-pyrazol-3-yl)pyridine, 1,4-H2BDC = 1,4-benzenedicarboxylic acid), has been synthesized and structurally characterized by single-crystal X-ray diffraction as well as elemental an