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A Manganese(Ⅱ) polymer {[Mn(bpdc)(bipy)(H2O)]·4.5H2O}n has been synthesized (bpdc=2,2-bipyridine- 3,3-dicarboxylate,bipy=4,4-bipyridine) and characterized by IR, UV, elemental analysis and X-ray crystal structure determination . It crystallizes in Mo