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报道了电化学聚合Ｎ，Ｎ－双水杨酸乙二胺合铁［ｐ－Ｆｅ（ｓａｌｅｎ）］一氧化氮（ＮＯ）超微传 感器的制备、ＮＯ的响应及机理研究．实验发现，用电化学聚合的方法制备的 ｐ－Ｆｅ（ｓａｌｅｎ）超微传感器对 ＮＯ的检测有高的灵敏度和好的选择性． ＮＯ的浓度在 ７． ２× １０－８～４． ４× １０－６ ｍｏｌ／Ｌ范围内，氧化电流与浓度呈线性关系；线性相关系数为０．９９９６，检测限达３．６×１０－８ ｍｏｌ／Ｌ；生物体中常见的物质如抗坏血酸、尿酸、儿茶酚胺类代谢产物、ＮＯ的氧化产物ＮＯ－２ 等不干扰测定．所研制的传感器可用于ＮＯ的在体分析．
The electrochemical preparation of N, N-bis-salicylic acid [p-Fe (salen)] nitric oxide (NO) sensor and the response and mechanism of NO were reported. It was found that the p-Fe (salen) nanosensor prepared by electrochemical polymerization has high sensitivity and good selectivity for NO detection. NO concentration of 7. 2 × 10-8 ~ 4. In the range of 4 × 10-6 mol / L, there was a linear relationship between the oxidation current and concentration, the linear correlation coefficient was 0.9996 and the detection limit was 3.6 × 10-8 mol / L. Common substances in organisms such as ascorbic acid, Uric acid, catecholamine metabolites, NO-oxidation products such as NO-2 do not interfere with the determination. The developed sensor can be used for NO in vivo analysis.