Bi-based superconductors fabricated in high magnetic fields

来源 :Transactions of Nonferrous Metals Society of China | 被引量 : 0次 | 上传用户:lyxdaisy
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The microstructure and superconducting properties of Bi-2223 superconductor fabricated in high magnetic fields were investigated. The results shows that the Bi-2212 grains with their c-axis parallel to the magnetic field were formed after the partial-melting and solidification in 8 T magnetic field, and transformed into the Bi-2223 grains with c-axis alignment during the further sintering process at 840 ℃ without magnetic field. The conversion of Bi-2212 grains to Bi-2223 grains has the heredity in grain alignment. The mixed structures of the Bi-2223 and the Bi-2212 grains with their c-axis parallel to the magnetic field are formed in samples sintered at 850?855 ℃ in 10 T magnetic field. When sintered in 10 T below 845 ℃, a high proportion of Bi-2223 phase is obtained, however no preferred orientation is observed. The Bi-2223 grains with their c-axis parallel to the axial direction of the vertical tube furnace are formed not only on the surface, but also in the center of the sample sintered at 850 ℃ for 120 h in a 15 ℃/cm temperature gradient without magnetic field. Moreover, the samples sintered in the temperature gradient and in a 10 T magnetic field have a stronger c-axis alignment of Bi-2223 phase. The microstructure and superconducting properties of Bi-2223 superconductor fabricated in high magnetic fields were investigated. The results shows that the Bi-2212 grains with their c-axis parallel to the magnetic field were formed after the partial-melting and solidification in 8 T magnetic field, and transformed into the Bi-2223 grains with c-axis alignment during the further sintering process at 840 ° C without magnetic field. The conversion of Bi-2212 grains to the heredity in grain alignment. The mixed structures of the Bi-2223 and the Bi-2212 grains with their c-axis parallel to the magnetic field were formed in a sample sintered at 850 ° C. 855 ° C. in 10 T magnetic field. When sintered in 10 T below 845 ° C., a high proportion of Bi -2223 phase is obtained, but no preferred orientation is observed. The Bi-2223 grains with their c-axis parallel to the axial direction of the vertical tube furnace are formed not only on the surface, but also in the center of the samp le sintered at 850 ° C for 120 h in a 15 ° C / cm temperature gradient without magnetic field. Moreover, the samples sintered in the temperature gradient and in a 10 T magnetic field have a stronger c-axis alignment of Bi-2223 phase.
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