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合成了三元混配配合物 [Cu(1,10 - phen) (L- Ile) (H2 O) ]NO3 (1,10 - phen=1,10 -邻菲咯啉 ,L- Ile=L-异亮氨酸 ) ,并用元素分析、X射线衍射、摩尔电导、红外、紫外等手段对混配配合物进行了表征。晶体结构分析表明 :配合物晶体的空间群为 P2 1,晶胞参数 :a=1.1835 (5 ) nm,b=0 .6 775 (5 ) nm,c=1.332 8(5 ) nm,β=90 .74 5 (5 )°,V=1.0 6 86 (10 ) mm3 ,μ=1.0 6 2 mm-1,Dc=1.4 11g/ cm3 ,F(0 0 0 ) =4 70 ,R=0 .0 5 5 1,Rw=0 .0 4 6 9。分子中 Cu( )离子与一个 L- Ile(N,O)配体、一个 1,10 - phen(N,N)配体及 H2 O(O)配位形成五配位的变形四方锥构型。
The ternary complex [Cu (1,10 - phen) (L - Ile) (H 2 O)] NO 3 (1,10 - phen = Isoleucine) were synthesized and characterized by means of elemental analysis, X-ray diffraction, molar conductance, infrared and UV. The crystal structure analysis shows that the space group of the complex crystal is P2 1 and the unit cell parameters are: a = 1.1835 (5) nm, b = 0.67675 (5) nm, c = 1.332 8 .74 5 (5) °, V = 1.0 6 86 (10) mm3, μ = 1.0 6 2 mm-1, Dc = 1.4 11 g / cm3, F (0 0 0) = 4 70, R = 5 1, Rw = 0 .0 4 6 9. Molecular coordination of Cu (superscript +) with a ligand of L - Ile (N, O), a ligand of 1,10 - phen (N, N) .