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采用硝 酸镧溶 液为滴定 剂,电导 滴定法确 定终点 测定磷 肥和复 混肥 中五氧 化二 磷的含量,滴定 适宜的 p H 值范 围为 4~ 7,在此范 围内钙 离子没有 干扰。本方 法测定的 回收率 在 995%~1005 % ,准确度 与重量 法接近,装 置简单 ,测定一 份浸取 液仅 需数分 钟,适 用于含 磷肥 料中总磷量、水 溶性磷 和有效磷 的测定 。
Lanthanum nitrate solution was used as titrant and conductance titration method was used to determine the content of P2O5 in phosphate fertilizer and compound fertilizer. The suitable p H value for titration ranged from 4 to 7, and calcium ions did not interfere in this range. The recovery rate measured by this method is between 99.5% and 100.5%, the accuracy is close to that of gravimetric method and the device is simple. Only a few minutes is needed to measure a leaching solution, which is suitable for total phosphorus content, water-soluble Determination of phosphorus and available phosphorus.