Molecular organic geochemical evidence for paleoenvironmental changes at 11.87—12.28 m in GS-1 sedim

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Organic lipids with different occurrence modes in a sedimentary core in a subtropicalfreshwater lake, Gucheng Lake, were sequentially extracted, separated and analyzed. Thedown-core variations of OEP index of alkanes, C_(18:2)/C_(18:0) ratios of fatty acids, ratios of boundfatty acids to free fatty acids, thermo-maturity indices of hopanoid hydrocarbons and relativeconcentrations of sedimentary minerals revealed an evident increasing in allochthonous inputfrom rock detritus below 12.28 m in the sedimentary profile. The distribution pattern of tightly-bound β-hydroxy fatty acids indicated a difference in bacterial communities above and below theboundary, as well as the gammacerane index may assign a significant change in lake watersalinity. The evidence, in general, suggested that a significant paleoenvironmental change hadtaken place in ca. 9.6 kaBP on the regional basis. The down-core variations of OEP index of alkanes, C_ (18: 2) / C_ (18: 0) ratios of fatty acids, ratios of bound fatty acids to free fatty acids, thermo-maturity indices of hopanoid hydrocarbons and relative concentrations of sedimentary minerals revealed an evident increasing in allochthonous input from rock detritus below 12.28 m in the sedimentary profile. -hydroxy fatty acids indicated a difference in bacterial populations above and below theboundary, as well as the gammacerane index may assign a significant change in lake watersalinity. The evidence, in general, suggested that a significant paleoenvironmental change hadtaken place in ca. 9.6 kaBP on the regional basis.
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