【摘 要】
：
A new bicadmium(Ⅱ) complex [Cd2L](ClO4)2·1.25H2O (C28H35Cd2Cl4N6O13.25) was synthesized and characterized by X-ray diffraction and ES mass spectral analyses.
【机 构】
：
Materials Chemistry Laboratory,Department of Chemical Engineering
论文部分内容阅读
A new bicadmium(Ⅱ) complex [Cd2L](ClO4)2·1.25H2O (C28H35Cd2Cl4N6O13.25) was synthesized and characterized by X-ray diffraction and ES mass spectral analyses. It crystallizes in the triclinic system, space group P1 with a = 15.630(3), b = 15.990(3), c = 16.330(3) A,α=89.90(3), β= 68.87(3), γ=(87.94(3)o, V = 3804.113 A3, Mr = 1034.22, Z = 4, F(000) = 2060, Dc = 1.806 g/cm3, T = 293(2) K,μ= 1.468 mm-1 and λ= 0.71073A. The structure was refined to R = 0.0779 and wR = 0.1960 for 7034 observed reflections with I > 2σ(I).
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