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A new compound(ClO_4)_2(H_2O)0.5(azpy)was synthesized.Its structure was determined by single X-ray diffraction.The crystal belongs to triclinic system,space group P1.The crystallographic data:a=11.813(2),b=12.574(2),c=14.580(3)*!,a=84.048(6),β=77.878(15),γ=67.902(12)°,V=1961.1(7)*!~3,Z=2,F(000)=926,Mr=904.57,Dc=1.532Mg/m~3,μ=0.542mm~(-1),R_1=0.0770,and wR_2=0.1373.In the ctystal Mn(Ⅱ)ion is coordinated with six nitrogen from three phen ligands to form a distorted octahedron geometry.
A new compound (ClO_4) _2 (H_2O) 0.5 (azpy) was synthesized. Its structure was determined by single X-ray diffraction. The crystal belongs to triclinic system, space group P1.The crystallographic data: a = 11.813 b = 12.574 (2), c = 14.580 (3) * !, a = 84.048 (6), β = 77.878 (15), γ = 67.902 (12) °, V = 1961.1 = 2, F (000) = 926, Mr = 904.57, Dc = 1.532 Mg / m ~ 3, μ = 0.542 mm -1, R_1 = 0.0770, and wR_2 = 0.1373.In the ctystal Mn (Ⅱ) ion is coordinated with six nitrogen from three phen ligands to form a distorted octahedron geometry.