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Three novel inorganic-organic hybrid materials,[Cu(imi)2(H2O)(MoO4)]n 1,[Cu2(imi)3(MoO4)2]n·nH2O 2 and [Cu3(imi)2(OH)2(MoO4)2]n 3(imi = imidazole),were synthesized and characterized by X-ray single-crystal structure determination.1 crystallizes in or