Study on Rare Earth Electrolyte of Ce0.9RE0.1O2-δ (RE=Pr, Nd, Sm, Gd, Dy)

来源 :Journal of Rare Earths | 被引量 : 0次 | 上传用户:ZXX198811
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The solid solutions Ce_(0.9)RE_(0.1)O_(2-δ)(RE=Pr, Nd,Sm, Gd, Dy) were prepared by sol-gel method. The XRD measurement shows that the solid solution is crystallized in cubic fluorite-type structure and the cell volume of Ce_(0.9)RE_(0.1)O_(2-δ) decreases with the increase of atomic number of RE. The ionic conduction for Ce_(0.9)RE_(0.1)O_(2-δ) was measured by impedance spectroscopy and Ce_(0.9)Pr_(0.1)O_(2-δ) has better conductivity. The linear thermal expansion of Ce_(0.9)RE_(0.1)O_(2-δ) decreases with the increase of atomic number of RE. The solid solutions Ce_ (0.9) RE_ (0.1) O_ (2-δ) (RE = Pr, Nd, Sm, Gd, Dy) were prepared by sol- gel method. The XRD measurement shows that the solid solution is crystallized in cubic (0) O_ (2-δ) decreases with the increase of atomic number of RE. The ionic conduction for Ce_ (0.9) RE_ (0.1) O_ ) was measured by impedance spectroscopy and Ce_ (0.9) Pr_ (0.1) O_ (2-δ) has better conductivity. The linear thermal expansion of Ce_ (0.9) RE_ (0.1) O_ number of RE.
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