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目前,碳酸氢铵在国内工业生产的氮肥中占有相当大的比例。但是由于多方面的原因,这种肥料在贮藏、运输和施用过程中,总是在不断的发生着分解损耗,故其利用率很低。显然,研究这一解体的热力学行为和动力学机理,对提高碳酸氢铵肥料的利用率是很有必要的。在“碳酸氢铵肥料不稳定性的探讨”一文中,对无水碳酸氢铵的热力学稳定性进行分析之后指出:在常温常压下,碳酸氢铵是稳定的,不会自动分解;并
At present, ammonium bicarbonate occupies a considerable proportion of nitrogenous fertilizer produced in the country. However, due to many reasons, the fertilizer is always undergoing decomposition loss during storage, transportation and application, so its utilization rate is very low. Obviously, studying the thermodynamic behavior and kinetic mechanism of this disintegration is necessary to improve the utilization rate of ammonium bicarbonate fertilizer. In the article “Discussion on the instability of ammonium bicarbonate fertilizer”, after analyzing the thermodynamic stability of anhydrous ammonium bicarbonate, it was pointed out that ammonium bicarbonate is stable and does not decompose automatically at normal temperature and pressure; and