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A new coordination polymer {[In(bdc)(OH)]·4H2O}n(H2bdc=1,4-benzenedi-carboxylic acid) has been synthesized through hydrothermal conditions,and was characterized by X-ray single-crystal diffraction and other measurements.The complex crystallizes in the orthorhombic system,space group Imma with a=18.3621(13),b=7.1932(5),c=11.8278(8),V=1562.24(19)3,Z=4.Dc=1.565g/cm3,Mr=368.00,F(000)=728,μ(MoKα)=1.542 mm-1,S=1.019,R=0.0468 and wR=0.1326 for 884 observed reflections(>2σ(Ⅰ)).The title compound represents a 3-D framework containing four kinds of tunnels in different shapes and sizes.
A new coordination polymer {[In (bdc) (OH)] · 4H2O} n (H2bdc = 1,4-benzenedi-carboxylic acid) has been synthesized through hydrothermal conditions, and was characterized by X-ray single- measurements.The complex crystallizes in the orthorhombic system, space group Imma with a = 18.3621 (13), b = 7.1932 (5), c = 11.8278 (8) , V = 1562.24 (19) 3, Z = = 1.565 g / cm3, Mr = 368.00, F (000) = 728, μ (MoKα) = 1.542 mm-1, S = 1.019, R = 0.0468 and wR = 0.1326 for 884 observed reflections (> 2σ (I)). The title compound represents a 3-D framework containing four kinds of tunnels in different shapes and sizes.