【摘 要】
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The title complex [Fc(OCH3)PS2Ir(cod)] (1, Fc = Fe(η5-C5K4)(η5-C5H5), cod =1,5-cyclooctadiene) has been prepared and characterized by X-ray diffraction analys
【机 构】
：
Institute of Molecular Engineering and Applied Chemistry
论文部分内容阅读
The title complex [Fc(OCH3)PS2Ir(cod)] (1, Fc = Fe(η5-C5K4)(η5-C5H5), cod =1,5-cyclooctadiene) has been prepared and characterized by X-ray diffraction analysis. It crystallizes in monoclinic, space group P21/n with a = 12.5567(5), b - 13.5197(5), c =11.7833(4) (A), β = 99.651(2)°, V = 1972.06(13) (A)3, Z = 4, Mr = 611.52, Dc = 2.06 g/cm3,μ(MoKα) - 7.775 mm-1, F(000) = 1184, S = 1.063, the final R - 0.0199 and wR = 0.0468 for 4063 observed reflections with I> 2σ(I) and 227 variables. The molecular structure of 1 shows that the central iridium atom is chelated by the [Fc(OCH3)PS2]- ligand via two sulfur atoms and coordinated by one η4-cod molecule via four carbon atoms in a distorted octahedral coordination geometry. The average Ir-S and Ir-C bond lengths are 2.3712(8) and 2.122(3) (A),respectively. is chel
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