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在水溶液中制备了络合物[Cu(H_2O)_2(en)][SO_4]的晶体,并在室温下测定了该晶体在近紫外—可见—近红外区域的电子吸收光谱。应用配位场理论以及3d轨道波函数径向标度理论定量地解释了晶体的电子吸收光谱。
The crystal of [Cu (H_2O) _2 (en)] [SO_4] complex was prepared in aqueous solution and the electron absorption spectra of the crystal in the near UV-Vis-NIR region were measured at room temperature. The coordination electron theory and the radial scale theory of 3d orbital wave function were used to quantitatively explain the electron absorption spectra of crystals.