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本文合成了含邻香草醛缩邻氨基苯甲酸席夫碱(H2L〕的配合物[Cu(HL)·Cl·H2O]2、[Co(HL)Cl·3H2O]、[NiL·H2O]2·2H2O和[ZnL·H2O]2·2H2O,通过元素分析、摩尔电导、红外光谱、电子光谱、磁比率及热分析等对配合物作了表征,研究了Cu配合物在低温下的多晶粉末和有机溶剂中的ESR波谱,并考察了配合物对的清除作用.
In this paper, the complexes of [Cu (HL) · Cl · H2O] 2, [Co (HL) Cl · 3H2O] and [NiL · H2O] 2 with Schiff base of o- 2H2O and [ZnL · H2O] 2 · 2H2O. The complex was characterized by elemental analysis, molar conductance, IR, electron spectroscopy, magnetic ratio and thermal analysis. The effects of Cu complex on polycrystalline powders at low temperature and ESR spectra in organic solvents and investigated the scavenging effect of the complexes.