前手性酮的对映选择性还原在不对称合成中占有极其重要的地位。人们对这类反应进行了广泛的研究，其中Ｉｔｓｕｎｏ和Ｃｏｒｙ等发现的用手性硼杂口恶唑烷催化不对称还原的方法，已成为高对映选择性还原羰基化合物最成功的方法之一［１，２］。近年来，国内外许多文献报道... Enantioselective reduction of prochiral ketones plays a very important role in the asymmetric synthesis. A wide range of studies have been conducted on this type of reaction, among which the method of asymmetric reduction catalyzed by chiral boronazooxazolidines discovered by Itsuno and Cory has become one of the most successful methods for the highly enantioselective reduction of carbonyl compounds [1,2]. In recent years, many domestic and foreign literature reports ...