【摘 要】
：
合成了标题化合物。该化合物的分子式[Ni(TSSB)(Bipy)H2O]4H2O(C19H27NiN3O9S),分子量532.21,采用单色化的MoK?(=0.71073?射线测定,共收集15601个数据,其中独立衍射点5371个(
【机 构】
：
广西师范大学化学化工系,桂林工学院材料与化学工程系,香港理工大学应用生物与化学科学系,广西师范大学化学化工系 桂林541004,桂林541004,香港,桂林541004
论文部分内容阅读
合成了标题化合物。该化合物的分子式[Ni(TSSB)(Bipy)H2O]4H2O(C19H27NiN3O9S),分子量532.21,采用单色化的MoK?(=0.71073?射线测定,共收集15601个数据,其中独立衍射点5371个(Rint=0.0316),I>2(I)可观测点数3537个,结果表明该化合物属单斜晶系,空间群P21/c,其晶胞参数为:a=16.406(2),b=15.409(2),c=9.252(1)?β=90.373,V=2338.9(6)?,Z=4,Dc=1.511g/cm3,=0.973mm-1,F(000)=1112,该配合物是六配位的变形八面体构型。
The title compound was synthesized. The molecular formula of the compound was Ni (TSSB) (Bipy) H2O H2O 4H2O (C19H27NiN3O9S) with a molecular weight of 532.21. A total of 15601 data were collected using monochromatic MoK? (= 0.71073? = 0.0316) and 3537 (I> 2) were observed. The results showed that the compound belongs to the monoclinic space group P21 / c with unit cell parameters of a = 16.406 (2) and b = 15.409 ), c = 9.252 (1)? β = 90.373, V = 2338.9 (6) ?, Z = 4, Dc = 1.511 g / cm3, = 0.973 mm-1 and F Coordination of the deformed octahedral configuration.
其他文献
The method of characteristics was adopted to analyze water level fluctuation existing in Bull-Horn surge chamber in reservoir-valve pipe system during waterhamm
A novel antimicrobial polypeptidc was isolated and charaeterized from loach,Misgurmis anguillieaudatus, The polypcptide, named MAPP, is a single-chain polypcpti
Amphiphilic block copolymers can exhibit rich and complex morphologies in aqueous solutions, but these structures are usually delicate, easily disturbed by comp
The electrocatalysts of Pt/C, PtRu/C and Ru/C were prepared by the impregnation method. The facet characterization, the dispersion and the particle size for the
The authors show that the self-similar set for a finite family of contractive similitudes (sim-ilarities, i.e., |fi(x) - fi(y)| = ai|x - y|, x,y ∈ RN, where 0
Crystalline TiO2 nanoparticles were synthesized by hydrolysis of titanium tetrabutoxidein the presence of hydrochloric aeid in NP-5 (lgepal CO-520)/ cyclohcxane
The synthesis and characterization of a new series of liquid crystalline polymers, poly(dicycloalkyl vinylterephthalate)s, are reported. The basic building bloc
A new phosphorylcholine, (6-hydroxy)hexyl-2-(trimethylammonio)ethyl phosphate (HTEP), was synthesized and characterized. Segmented polyurethane (SPU) containing
The authors study the bifurcation problems of rough heteroclinic loop connecting threesaddle points for the case β1 ＞ 1, β2 ＞ 1, β3 ＜ 1 and β1β2β3 ＜ 1. The ex
Some geometric behaviours of complete solutions to mean curvature flow before the singu-larities occur are studied. The author obtains the estimates of the rate