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由于对日趋严重的温室效应的担忧,对廉价二氧化碳的固定和转化成为一个非常有吸引力的研究领域。本文主要介绍了二氧化碳参与的有机化学反应,包括与环氧化合物、胺类化合物、不饱和碳氢化合物以及醇类和烃类等化合物的反应。文章分别对这几类反应的发展历程、研究现状进行了总结,重点介绍了各反应所用到的催化剂体系及有关反应机理,并展望了该领域的研究前景。
Due to growing concerns about the greenhouse effect, the fixation and conversion of cheap carbon dioxide has become a very attractive area of research. This article describes the organic chemical reactions involved in CO2, including reactions with epoxides, amines, unsaturated hydrocarbons, and compounds such as alcohols and hydrocarbons. The article summarizes the development history and research status of these types of reactions respectively, especially the catalyst system and related reaction mechanism used in each reaction, and looks forward to the research prospects in this field.