A full-order sliding mode control based on a fuzzy extended state observer is proposed to control the uncertain chaos in the permanent magnet synchronous motor. Through a simple coordinate transformation, the chaotic PMSM model is transformed into the Brunovsky canonical form, which is more suitable for the controller design. Based on the fuzzy control theory, a fuzzy extended state observer is developed to estimate the unknown states and uncertainties, and the restriction that all the system states should be completely measurable is avoided. Thereafter, a full-order sliding mode controller is designed to ensure the convergence of all system states without any chattering problem. Comparative simulations show the effectiveness and superior performance of the proposed control method.