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0前言多原子桥联配体的多核配合物中,顺磁离子间磁偶合作用的研究对阐明磁性和结构的关系以及设计新型分子基磁性材料具有重要的理论意义。草酸根及草酰胺桥根桥联的多核配合物得到了较为广泛和深入的研究[1-5]。为了研究硫原子取代氧原子后,桥基对传递磁交换作用...
0 Preface The study of magnetic coupling between paramagnetic ions in polynuclear complexes of polyatomic bridging ligands is of great theoretical significance for elucidating the relationship between magnetism and structure and for designing novel molecular-based magnetic materials. Oxalic acid and oxalic acid bridged bridged multinuclear complex has been more extensive and in-depth study [1-5]. In order to study the sulfur atoms to replace the oxygen atom, the bridge to the transfer of magnetic exchange ...