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研究了不同碱化度、不同铝铁比的聚合氯化铝铁(PAFC) 溶液的pH 驰豫、电导率变化,可见光谱及絮凝效果等物理化学性质。提出了B≥1 .5 后,Al( Ⅲ) 、Fe( Ⅲ)多核羟合配离子迅速交叉共聚形成高聚物的假设。通过稳定性观察,作出了对PAFC 工业化生产具有指导意义的稳定性—pH(B) —nAl/nFe 关系图。
The physicochemical properties, such as pH relaxation, conductivity change, visible spectrum and flocculation effect, were studied in different aluminum and aluminum alkalis. Proposed B ≥ 1. 5, the assumption that Al (Ⅲ) and Fe (Ⅲ) polynuclear complex ion rapidly cross-copolymerize to form polymer. Through the observation of stability, the stability-pH (B) -nAl / nFe diagram, which is of guiding significance for the industrial production of PAFC, has been made.