有机硼化合物是一种重要的有机合成中间体,有机硼酸及其衍生物可以被很容易的转化为一系列的功能性化合物并保持其空间构型不变.铜催化的α,β-不饱和化合物和联硼酸酯的不对称加成反应已经成为一个新颖的合成手性有机硼化合物的方法.综述了铜催化的α,β-不饱和化合物的不对称共轭硼化研究进展,其中包括了双膦配体、卡宾配体以及其它配体诱导的共轭硼化反应. Organoboron compounds are important organic synthesis intermediates and organoboronic acid and its derivatives can be easily transformed into a series of functional compounds and maintain their spatial configuration unchanged.Copper-catalyzed α, β-unsaturated The asymmetric addition reaction of compounds with boronic esters has become a novel method for the synthesis of chiral organoboron compounds. The progress of asymmetric conjugation boronization of copper-catalyzed α, β-unsaturated compounds is reviewed, including Conjugated boronation induced by bisphosphine ligands, carbene ligands and other ligands.