Synthesis and luminescence properties of europium activated Ca_3Al_2O_6-Sr_3Al_2O_6 system

来源 :Journal of Rare Earths | 被引量 : 0次 | 上传用户:xpzcz1992
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Divalent europium activated tristrontium dialuminum hexaoxide phosphor, (Sr1-xEux)3Al2O6, was obtained by solid state reaction. Crystal structure and luminescence properties of synthesized (Sr1-xEux)3Al2O6 were investigated. The major excitation band of (Sr1-xEux)3Al2O6 located in blue light region, the photoluminescence spectrum showed red light emission peaked at 618 nm which could be attributed to the d-f transition of the Eu2+. The influence of Ca2+ substitution for Sr2+ on structural and luminescence properties of Eu2+ doped Sr3Al2O6 was also studied. The photoluminescence peak position of (Sr1-yCay)2.94Eu0.06Al2O6 varied from 618 to 655 nm with increasing y value. The reason for redshift in the emission band of (Sr1-yCay)2.94Eu0.06Al2O6 phosphor was also discussed. Divalent europium activated tristrontium dialuminum hexaoxide phosphor, (Sr1-xEux) 3Al2O6, was obtained by solid state reaction. Crystal structure and luminescence properties of synthesized (Sr1-xEux) 3Al2O6 were investigated. The major excitation band of (Sr1-xEux) 3Al2O6 was in blue light region, the photoluminescence spectrum showed red light emission peaked at 618 nm which could be attributed to the df transition of the Eu2 +. The influence of Ca2 + substitution for Sr2 + on structural and luminescence properties of Eu2 + doped Sr3Al2O6 was also studied. Peak position of (Sr1-yCay) 2.94Eu0.06Al2O6 varied from 618 to 655 nm with increasing y value. The reason for redshift in the emission band of (Sr1-yCay) 2.94Eu0.06Al2O6 phosphor was also discussed.
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