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In order to demonstrate the effect of the sixth axial ligand on the biological funtionof heme proteins, we have determined the formal potentials and electron transfer numbersof imidazole (Im), 1-methylimidazole (1-MeIm) and 1-ethylimidazole (1-EtIm) complexes ofcytochrome c(cyt c) with an optically transparent thin-layer electrode.
In order to demonstrate the effect of the sixth axial ligand on the biological funtion of heme proteins, we have determined the formal potentials and electron transfer numbers of imidazole (Im), 1-methylimidazole (1-MeIm) and 1-ethylimidazole (1-EtIm) complexes ofcytochrome c (cyt c) with an optically transparent thin-layer electrode.