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N, N'', N''-Tris-(2-oxynaphthalidene)-tris-(2-iminoethyl) amine (TOTIA) has been synthesized and characterized by X-ray crystallography, and its crystal is of monoclinic, space group P21/c with a = 6.0158(5), b = 16.3851(2), c = 31.6650(3)