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Single crystal silicon substrate was modified with self-assembled monolayer of 3-aminopropyl-trimethylsilane by aqueous phase silanization. Colloidal gold nanoparticles(12.0±1.0 nm) were adsorbed on such an amino-terminated surface with a submonolayer coverage. Randomly distributed gold nanoparticles were reorganized into two-dimensional close-packed aggregates when treated with alkanthiol molecules.Large size two dimensional domains or ring like structures of gold nanoparticles can be induced by solvent flow and evaporation.
Single crystal silicon substrate was modified with self-assembled monolayer of 3-aminopropyl-trimethylsilane by aqueous phase silanization. Colloidal gold nanoparticles (12.0 ± 1.0 nm) were adsorbed on such an amino-terminated surface with a submonolayer coverage. Randomly distributed gold nanoparticles were reorganized into two-dimensional close-packed aggregates when treated with alkanthiol molecules. Large size two dimensional domains or ring like structures of gold nanoparticles can be induced by solvent flow and evaporation.