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以过硫酸铵（ＡＰＳ）为引发剂，对丙烯酸甲酯（ＭＡ）的乳液聚合进行了研究，得出在ＭＡ／Ｈ２Ｏ重量比为０．５时，６０℃下合成粒径分布均匀的聚丙烯酸甲酯（ＰＭＡ）种子乳液的最佳配方为：十二烷基硫酸钠（ＳＤＳ）、（ＡＰＳ）和（ＮａＨＣＯ３）的浓度分别为１１．６、１．７２和４．６９ｍｍｏｌ／Ｌ．然后以ＰＭＡ乳液为种子，以油溶性偶氮二异丁腈（ＡＩＢＡ）为引发剂，分别进行不溶胀与溶胀条件下醋酸乙烯酯（ＶＡ）的种子乳液聚合，并以磷钨酸为染色剂，用透射电子显微镜（ＴＥＭ）对胶粒形态进行了表征
The emulsion polymerization of methyl acrylate (MA) with ammonium persulfate (APS) as the initiator was studied. The results showed that at a weight ratio of MA / H2O of 0.5, polyacrylic acid with uniform particle size distribution was synthesized at 60 ℃. The best formulation of PMA seed emulsion was sodium dodecyl sulfate (SDS), (APS) and (NaHCO3) at concentrations of 11.6, 1.72 and 4.69 mmol / L, respectively. Then PMA emulsion was used as seed and oil-soluble azobisisobutyronitrile (AIBA) as initiator to separate the seed emulsion polymerization of vinyl acetate (VA) under non-swelling and swelling conditions, The morphology of colloidal particles was characterized by transmission electron microscopy (TEM)