【摘 要】
：
The kinedtics of protonolysis of o-subnitutal phenylmercuric chlorides, o-XC6H4HgCl (X = H, CH3, CH3O, C2H5O, CF3, COOC2H5, Cl, Br, F, NO2), by hydrochloric aci
【出 处】
：
Chinese Chemical Letters
论文部分内容阅读
The kinedtics of protonolysis of o-subnitutal phenylmercuric chlorides, o-XC6H4HgCl (X = H, CH3, CH3O, C2H5O, CF3, COOC2H5, Cl, Br, F, NO2), by hydrochloric acid in the presence of sodium iodide as catalyst have been studied in ethanol. The reaction bas been found to be second order ovetall, first order in cach reactant. The rate constants k measured at the same temperature may be arranged in the following order: C2H5O > CH3O > CH3 > H > CO2C2H5 >F > Cl > Br > CF3 > NO2
The kinedtics of protonolysis of o-subnitutal phenylmercuric chlorides, o-XC6H4HgCl (X = H, CH3, CH3O, C2H5O, CF3, COOC2H5, Cl, Br, F, NO2), by hydrochloric acid in the presence of sodium iodide as catalyst have has been studied in ethanol. The reaction const been found to be second order ovetall, first order in cach reactant. The rate constants k measured at the same temperature may be arranged in the following order: C2H5O> CH3O> CH3> H> CO2C2H5> F > Cl> Br> CF3> NO2
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