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The complexes of 3-methoxy-2-nitrobenzoates of Pr(III), Nd(III), Sm(III), Eu(III), Gd(III), Tb(III), Er(III) and Tm(III) with the formula: Ln(C8H6NO5)3·2H2O, where Ln=lanthanides(III), were synthesized and characterized by elemental analysis, Forier transform irtrared (FTIR) spectroscopy, magnetic and thermogravimetric studies and also by X-ray diffraction (XRD) measurements. The complexes had col- ours typical for Ln(III) ions. The carboxylate groups bound as bidentate chelating. On heating to 1173 K in air they decomposed in the same way, at first, dehydrated in one step to anhydrous salts, and then decomposed to the oxides of respective metals with intermediate formation of the oxycarbonates. The enthalpy values of the dehydration process changed from 133.72 to 44.50 kJ/mol. Their solubility in water at 293 K was of the order of 10-4 mol/dm3. The magnetic moments of analysed complexes were determined by Gouy’s method in the range of 76-303 K.
The complexes of 3-methoxy-2-nitrobenzoates of Pr (III), Nd (III), Sm (III), Eu (III), Gd (III), Tb (III) with the formula: Ln (C8H6NO5) 3.2H2O, where Ln = lanthanides (III), synthesized and characterized by elemental analysis, Forier transform irtrared (FTIR) spectroscopy, magnetic and thermogravimetric studies and also by X-ray diffraction measurements. Theses had col- ours typical for Ln (III) ions. The carboxylate groups bound as bidentate chelating. On heating to 1173 K in air they decomposed in the same way, at first, dehydrated in one step to anhydrous salts, and The enthalpy values of the dehydration process changed from 133.72 to 44.50 kJ / mol. Their solubility in water at 293 K was the order of 10-4 mol / dm3. The magnetic moments of the analyzed complexes were determined by Gouy’s method in the range of 76-303 K.