We present an improved approach to determine the zero-dispersion wavelength by measurement of the four-wave mixing (FWM) effect employing the two-tunable-laser scanning method. The FWM behaviour of combined fibres with two different zero-dispersion wavelengths is investigated theoretically and experimentally. The results are compared with those by regular zero-dispersion wavelength test instrument using phase shift technique. The theoretical and experimental results confirm the feasibility of determination of zero-dispersion wavelength by FWM.