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研究电荷转移复合物的方法已有很多报道。前文曾报道了气相渗透法,由于操作较烦,不宜快速测定。色谱法也曾有文献报道,但要求参与电荷转移复合反应化合物之一制成固定相,带来了两个缺点:其一制备色谱柱工作量很大。其二在柱内进行的复合反应是非均相的,与均相测量结果差别很大。本文是探索一种既准确又快速的色谱法。不仅能研究电荷转移复合物,同时用于色谱基本理论研究,也是很有价值的。
Methods for studying charge-transfer complexes have been reported. The previous article has reported the gas penetration method, due to the operation more annoying, should not be measured quickly. Chromatography has also been reported in the literature, but requiring one of the charge-transfer complexing compounds to make the stationary phase entails two disadvantages: a heavy column preparation. The second composite reaction in the column is heterogeneous, and the results of homogeneous measurements vary widely. This article explores an accurate and fast chromatography method. It is also valuable to study not only charge-transfer complexes but also basic theory of chromatography.