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自1990年Kratschmer及其合作者找到了宏观量制备C60的方法以来,已人工合成出40多种含C60配体的过渡金属有机化合物,尽管目前合成上取得的成就令人鼓舞,但是对过渡金属富勒烯化合物的动力学行为还未被系统研究[1].文献报道过渡金属C60衍生物已在许多均相催化反应中表现出优良的?
Since Kratschmer and his collaborators found a macroscopic approach to C60 production in 1990, more than 40 transition metal-organic compounds containing C60 ligands have been synthesized and, although the current synthesis is encouraging, the transition metal The kinetic behavior of fullerene compounds has not been systematically investigated.1 It has been reported in the literature that transition metal C60 derivatives have shown excellent performance in many homogeneous catalysis reactions.