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Chiral Imine Radical Mediated Enantioselective α-Alkynylation of β-Ketocarbonyls via Oxidative Decar
[会议论文] 作者：DehongWang[1]LongZhang[2]SanzhongLuo[2],
来源：中国化学会第30届学术年会 年份：2016
The first organocatalytic enantioselective direct α-Alkynylation of β-Ketocarbonyls via oxidative decarboxylation coupling is described.In the current rea...
[会议论文] 作者：DehongWang[1]LongZhang[2]SanzhongLuo[2],
来源：第十二届全国物理有机化学学术会议 年份：2017
A distinctive 5πe-carbonyl activation mode is reported on the basis of SET oxidation of a secondary enamine.The resulted β-enaminyl radical intermediate w...
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