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Oxygen activation by homoprotocatechuate 2,3-dioxygenase Reaction mechanism and role of the substrat
[会议论文] 作者：Wenzhen Lai,Geng Dong,Lili Cao,
来源：第14届全国化学动力学会议 年份：2015
Homoprotocatechuate 2,3-dioxygenase (HPCD) is a mononuclear non-heme iron enzyme that activates dioxygen to carry out the extradiol ring cleavage of its substra...
Multiple Low-Lying States for Compound Ⅰ of P450cam and Chloroperoxidase Revealed from Multireferenc
[会议论文] 作者：Hui Chen,Jinshuai Song,Wenzhen Lai,Wei Wu,Sason Shaik,
来源：中国化学会第二十七届学术年会 年份：2010
In this work we employed the multireference ab initio CASPT2/MM approach to systematically study the ground and low-lying excited states of important oxoiron(Ⅳ)-porphyrin cation-radical active species...
[会议论文] 作者：Binju Wang,Jiarui Lu,Kshatresh Dutta Dubey,Geng Dong,Wenzhen Lai,Sason Shaik,
来源：中国化学会第30届学术年会 年份：2016
The iron(Ⅳ)-oxointermediate has been amply established as the principal oxidant in non-heme enzymes and the key player in C-H bond activations and functionalizations.In contrast to this status,our pre...
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