As the selective introduction of a fluorine atom or a fluoroalkyl group into an organic molecule often brings about beneficial effects,the development of efficient protocols for enantioselective construction of chiral carbon stereocenters bearing a fluorine element is of current interests and highly desirable.With our continuous efforts in catalytic asymmetric synthesis of tetrasubstituted carbon stereocenters,we are interested in exploiting new asymmetric reactions to fully substituted chiral carbons featuring a fluoroalkyl substituent.