Copper-Catalyzed Oxidative Coupling of Alkenes with AldehydesDirect Access to α,β-Unsaturated Ketone

来源 :第十届全国物理有机化学学术会议 | 被引量 : 0次 | 上传用户：mj19830512

【摘要】

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The first Cu-catalyzed oxidative coupling of alkenes and aldehydes was demonstrated.Various aldehydes were utilized as substrates to construct α,β-unsaturated

【作者】

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Jing Wang Chao Liu Aiwen Lei

【机构】

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CollegeofChemistryandMolecularSciences,WuhanUniversity,Wuhan,Hubei,430072

【出处】

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第十届全国物理有机化学学术会议

【发表日期】

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2013年9期

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论文部分内容阅读

The first Cu-catalyzed oxidative coupling of alkenes and aldehydes was demonstrated.Various aldehydes were utilized as substrates to construct α,β-unsaturated ketones with alkenes.Preliminary mechanistic study indicates that this reaction is likely to proceed via a single electron transfer process.

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Copper-Catalyzed Oxidative Coupling of Alkenes with AldehydesDirect Access to α,β-Unsaturated Ketone

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