取代茚衍生物与羰基铼化合物的反应研究

来源 :中国化学会全国第十二届有机合成化学学术研讨会 | 被引量 : 0次 | 上传用户：quanxi111

【摘要】

：

　　与环戊二烯相比，茚的配位形式更具多样性。目前已经发现的茚配体的配位形式超过了十种[1]，且含有茚基的过渡金属配合物比含有环戊二烯基的过渡金属配合物具有更高的反应活

【作者】

：

张新利韩占刚林进郑学忠马志宏李素贞

【机构】

：

河北师范大学化学与材料科学学院石家庄 050016

【出处】

：

中国化学会全国第十二届有机合成化学学术研讨会

【发表日期】

：

2015年期

【关键词】

：

取代茚基配体衍生物羰基铼化合物过渡金属配合物配位形式环戊二烯基反应活性

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论文部分内容阅读

　　与环戊二烯相比，茚的配位形式更具多样性。目前已经发现的茚配体的配位形式超过了十种[1]，且含有茚基的过渡金属配合物比含有环戊二烯基的过渡金属配合物具有更高的反应活性和催化性能[2-3]。本文研究了两种单取代茚基配体与羰基铼化合物的反应，分别合成了[(η5-C9H6R)Re(CO)3] [R = C6H4OCH3(1)； CH(CH2)4(2)]两个单核化合物。

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取代茚衍生物与羰基铼化合物的反应研究

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